1. Ktisis Cyprus University of Technology
  2. Cyprus University of Technology (Research Output)
  3. Άρθρα/Articles
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Πεδίο DCΤιμήΓλώσσα
dc.contributor.authorPassadis, Stamatis S.-
dc.contributor.authorTsiafoulis, Constantinos G.-
dc.contributor.authorDrouza, Chryssoula-
dc.contributor.authorTsipis, Athanassios C.-
dc.contributor.authorMiras, Haralampos N.-
dc.contributor.authorKeramidas, Anastasios D.-
dc.contributor.authorKabanos, Themistoklis A.-
dc.date.accessioned2017-01-16T12:27:18Z-
dc.date.available2017-01-16T12:27:18Z-
dc.date.issued2016-02-15-
dc.identifier.citationInorganic Chemistry, 2016, vol. 55, no. 4, pp. 1364-1366en_US
dc.identifier.issn1520510X-
dc.identifier.urihttps://hdl.handle.net/20.500.14279/9060-
dc.description.abstractReaction of the oxidovanadium(IV)-LN-N species (LN-N is bipy = 2,2′-bipyridine or bipy-like molecules) with either BF4- or HF and/or KF results in the formation of compounds of the general formula cis-[VIV(=O)(F)(LN-N)2]+. Structural and spectroscopic (electron paramagnetic resonance) characterization shows that these compounds are in the tetravalent oxidation state containing a terminal fluorido ligand. Density functional theory calculations reveal that the VIV-F bond is mainly electrostatic, which is reinforced by reactivity studies that demonstrate the nucleophilicity of the fluoride ligand in a halogen exchange reaction and in fluorination of various organic substrates.en_US
dc.formatpdfen_US
dc.language.isoenen_US
dc.relation.ispartofInorganic Chemistryen_US
dc.rights© American Chemical Societyen_US
dc.subjectOxidationen_US
dc.subjectOxidovanadiumen_US
dc.subjectGeneral formulaen_US
dc.titleSynthesis, Bonding, and Reactivity of Vanadium(IV) Oxido-Fluorido Compounds with Neutral Chelate Ligands of the General Formula cis-[VIV(=O)(F)(LN-N)2]+en_US
dc.typeArticleen_US
dc.collaborationCyprus University of Technologyen_US
dc.collaborationUniversity of Ioanninaen_US
dc.subject.categoryAgricultural Biotechnologyen_US
dc.journalsSubscriptionen_US
dc.countryGreeceen_US
dc.countryCyprusen_US
dc.subject.fieldAgricultural Sciencesen_US
dc.publicationPeer Revieweden_US
dc.identifier.doi10.1021/acs.inorgchem.5b02895en_US
dc.relation.issue4en_US
dc.relation.volume55en_US
cut.common.academicyear2015-2016en_US
dc.identifier.spage1364en_US
dc.identifier.epage1366en_US
item.grantfulltextnone-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.openairecristypehttp://purl.org/coar/resource_type/c_6501-
item.openairetypearticle-
item.fulltextNo Fulltext-
crisitem.journal.journalissn1520-510X-
crisitem.journal.publisherAmerican Chemical Society-
crisitem.author.deptDepartment of Agricultural Sciences, Biotechnology and Food Science-
crisitem.author.facultyFaculty of Geotechnical Sciences and Environmental Management-
crisitem.author.orcid0000-0002-2630-4323-
crisitem.author.parentorgFaculty of Geotechnical Sciences and Environmental Management-
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