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https://hdl.handle.net/20.500.14279/1628
Title: | p-Hydroquinone-metal compounds: Synthesis and crystal structure of two novel VV-p-hydroquinonate and VIV-p-semiquinonate species |
Authors: | Tolis, Vagelis Gramlich, Volker Drouza, Chryssoula |
Major Field of Science: | Agricultural Sciences |
Field Category: | AGRICULTURAL SCIENCES;Agricultural Biotechnology;Other Agricultural Sciences |
Keywords: | Hydroquinone;Quinone;Quinone--Derivatives;Chemical reactions;Chemical structure |
Issue Date: | 7-Dec-2002 |
Source: | Chemical communications, 2002, no. 23, pp. 2786-2787 |
Volume: | 23 |
Start page: | 2786 |
End page: | 2787 |
Journal: | Chemical communications |
Abstract: | Reaction of the p-hydroquinone derivative H2Na4bicah·4H2O with either VIVOSO4·3H2O and NaVVO3 in equivalent quantities or with NaVVO3 yields the tetranuclear VIVO2+ macrocycle-semiquinonate compound Na6{(VIVO)4-(μ2-O) 2[μ2-bicas·(-5)-N,O,O,O]2}·Na 2SO4·20H2O (1·Na2SO4·20H2O) and the dinuclear cis-VVO2+-hydroquinone species Na4{(VVO2)2[μ2- bicah(-6)-N,O,O,O]}·11H2O (2·11H2O) respectively. Compounds 1·Na2SO4·20H2O and 2·11H2O were characterized by X-ray structure analysis and ab initio calculations |
URI: | https://hdl.handle.net/20.500.14279/1628 |
ISSN: | 13597345 |
DOI: | 10.1039/B207330G |
Rights: | © The Royal Society of Chemistry |
Type: | Article |
Affiliation: | University of Cyprus |
Affiliation : | University of Cyprus University of Ioannina Aristotle University of Thessaloniki Laboratory of Crystallography National Center for Scientific Research Demokritos |
Publication Type: | Peer Reviewed |
Appears in Collections: | Άρθρα/Articles |
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