Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.14279/1496
Title: Investigation on uranyl interaction with bioactive ligands. Synthesis and structural studies of the uranyl complexes with glycine and N-(2-mercaptopropionyl)glycine
Authors: Keramidas, Anastasios D. 
Rikkou, Maria P. 
Drouza, Chryssoula 
Major Field of Science: Agricultural Sciences
Field Category: AGRICULTURAL SCIENCES;Agricultural Biotechnology;Other Agricultural Sciences
Keywords: Carboxylic acids;Glycine;Ligands;Uranium;Infrared spectroscopy;Nuclear magnetic resonance spectroscopy;Solid state;X-ray crystallography
Issue Date: 2002
Source: Radiochimica Acta, 2002, vol. 90, no. 9-11, pp. 549-554
Volume: 90
Issue: 9-11
Start page: 549
End page: 554
Journal: Radiochimica Acta 
Abstract: Three new uranium(VI) compounds have been prepared with glycine (Hgly), N-(2-mercaptopropionyl)glycine (Hmpg) and 2,2′-dithiobis(N-propionylglycine) (tpg). The crystal structure of [UO2(Hgly)2Cl2] has been solved, revealing the uranium atom to be seven-co-ordinated. The two zwitterionic glycines are coordinated to uranium atom by the carboxylate groups, one in a monodentate and the other in a bidentate mode. Solid state studies and low temperature 1H, 13C, 2D COSY and HMQC solution NMR spectra of the [UO2(mpg)(CH3COO)], show that mpg coordinates uranium atom by the carboxylate group
URI: https://hdl.handle.net/20.500.14279/1496
ISSN: 00338230
DOI: 10.1524/ract.2002.90.9-11_2002.549
Rights: Copyright © Oldenbourg Wissenschaftsverlag GmbH
Type: Article
Affiliation: University of Cyprus 
Affiliation : University of Cyprus 
Institute of Materials Science 
Appears in Collections:Άρθρα/Articles

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