1. Ktisis Cyprus University of Technology
  2. Cyprus University of Technology (Research Output)
  3. Άρθρα/Articles
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Πεδίο DCΤιμήΓλώσσα
dc.contributor.authorNicolaides, Antonis-
dc.contributor.authorSoulimane, Tewfik-
dc.contributor.authorVarotsis, Constantinos-
dc.date.accessioned2019-05-18T19:07:12Z-
dc.date.available2019-05-18T19:07:12Z-
dc.date.issued2019-
dc.identifier.citationRSC Advances, 2019, Vol. 9, No. 9, pp. 4776-4780en_US
dc.identifier.issn20462069-
dc.description.abstractA reversible temperature-dependent high-spin to low-spin transition with T 1/2 =-60 °C has been observed in the resonance Raman spectra of the equilibrium reduced and photoreduced heme a 3 of the thermophilic ba 3 heme-copper oxidoreductase. The transition is based on the frequency shifts of the spin-state marker bands ν 2 (C b C b ) and ν 10 (C a C m ) and is attributed to the displacement of the heme iron along the heme normal as a consequence of the Fe-Np repulsion at temperature below-40 °C which will increase the ligand field strength forcing the pairing of d electrons into the lower energy orbitals.en_US
dc.formatpdfen_US
dc.language.isoenen_US
dc.relation.ispartofRSC Advancesen_US
dc.rights© The Royal Society of Chemistry.en_US
dc.subjectBarium alloysen_US
dc.subjectBinary alloysen_US
dc.subjectCalcium alloysen_US
dc.subjectCopper alloysen_US
dc.titleReversible temperature-dependent high- to low-spin transition in the heme Fe–Cu binuclear center of cytochrome ba3 oxidaseen_US
dc.typeArticleen_US
dc.collaborationCyprus University of Technologyen_US
dc.collaborationUniversity of Limericken_US
dc.subject.categoryChemical Sciencesen_US
dc.journalsOpen Accessen_US
dc.countryCyprusen_US
dc.countryIrelanden_US
dc.subject.fieldNatural Sciencesen_US
dc.publicationPeer Revieweden_US
dc.identifier.doi10.1039/c8ra09954een_US
dc.relation.issue9en_US
dc.relation.volume9en_US
cut.common.academicyear2018-2019en_US
dc.identifier.spage4776en_US
dc.identifier.epage4780en_US
item.fulltextWith Fulltext-
item.languageiso639-1en-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_6501-
item.cerifentitytypePublications-
item.openairetypearticle-
crisitem.journal.journalissn2046-2069-
crisitem.journal.publisherRoyal Society of Chemistry-
crisitem.author.deptDepartment of Chemical Engineering-
crisitem.author.deptDepartment of Chemical Engineering-
crisitem.author.facultyFaculty of Geotechnical Sciences and Environmental Management-
crisitem.author.facultyFaculty of Geotechnical Sciences and Environmental Management-
crisitem.author.orcid0000-0003-2771-8891-
crisitem.author.parentorgFaculty of Geotechnical Sciences and Environmental Management-
crisitem.author.parentorgFaculty of Geotechnical Sciences and Environmental Management-
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