Please use this identifier to cite or link to this item:
https://hdl.handle.net/20.500.14279/13677
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Nicolaides, Antonis | - |
dc.contributor.author | Soulimane, Tewfik | - |
dc.contributor.author | Varotsis, Constantinos | - |
dc.date.accessioned | 2019-05-18T19:07:12Z | - |
dc.date.available | 2019-05-18T19:07:12Z | - |
dc.date.issued | 2019 | - |
dc.identifier.citation | RSC Advances, 2019, Vol. 9, No. 9, pp. 4776-4780 | en_US |
dc.identifier.issn | 20462069 | - |
dc.description.abstract | A reversible temperature-dependent high-spin to low-spin transition with T 1/2 =-60 °C has been observed in the resonance Raman spectra of the equilibrium reduced and photoreduced heme a 3 of the thermophilic ba 3 heme-copper oxidoreductase. The transition is based on the frequency shifts of the spin-state marker bands ν 2 (C b C b ) and ν 10 (C a C m ) and is attributed to the displacement of the heme iron along the heme normal as a consequence of the Fe-Np repulsion at temperature below-40 °C which will increase the ligand field strength forcing the pairing of d electrons into the lower energy orbitals. | en_US |
dc.format | en_US | |
dc.language.iso | en | en_US |
dc.relation.ispartof | RSC Advances | en_US |
dc.rights | © The Royal Society of Chemistry. | en_US |
dc.subject | Barium alloys | en_US |
dc.subject | Binary alloys | en_US |
dc.subject | Calcium alloys | en_US |
dc.subject | Copper alloys | en_US |
dc.title | Reversible temperature-dependent high- to low-spin transition in the heme Fe–Cu binuclear center of cytochrome ba3 oxidase | en_US |
dc.type | Article | en_US |
dc.collaboration | Cyprus University of Technology | en_US |
dc.collaboration | University of Limerick | en_US |
dc.subject.category | Chemical Sciences | en_US |
dc.journals | Open Access | en_US |
dc.country | Cyprus | en_US |
dc.country | Ireland | en_US |
dc.subject.field | Natural Sciences | en_US |
dc.publication | Peer Reviewed | en_US |
dc.identifier.doi | 10.1039/c8ra09954e | en_US |
dc.relation.issue | 9 | en_US |
dc.relation.volume | 9 | en_US |
cut.common.academicyear | 2018-2019 | en_US |
dc.identifier.spage | 4776 | en_US |
dc.identifier.epage | 4780 | en_US |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.openairecristype | http://purl.org/coar/resource_type/c_6501 | - |
item.openairetype | article | - |
item.languageiso639-1 | en | - |
crisitem.journal.journalissn | 2046-2069 | - |
crisitem.journal.publisher | Royal Society of Chemistry | - |
crisitem.author.dept | Department of Chemical Engineering | - |
crisitem.author.dept | Department of Chemical Engineering | - |
crisitem.author.faculty | Faculty of Geotechnical Sciences and Environmental Management | - |
crisitem.author.faculty | Faculty of Geotechnical Sciences and Environmental Management | - |
crisitem.author.orcid | 0000-0003-2771-8891 | - |
crisitem.author.parentorg | Faculty of Geotechnical Sciences and Environmental Management | - |
crisitem.author.parentorg | Faculty of Geotechnical Sciences and Environmental Management | - |
Appears in Collections: | Άρθρα/Articles |
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File | Description | Size | Format | |
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c8ra09954e.pdf | Fulltext | 808.12 kB | Adobe PDF | View/Open |
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