1. Ktisis Cyprus University of Technology
  2. Cyprus University of Technology (Research Output)
  3. Άρθρα/Articles
Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.14279/1127
DC FieldValueLanguage
dc.contributor.authorStavrakis, Stavros-
dc.contributor.authorVarotsis, Constantinos-
dc.contributor.authorKoutsoupakis, Constantinos-
dc.contributor.otherΣταυράκης, Σταύρος-
dc.contributor.otherΒαρώτσης, Κωνσταντίνος-
dc.contributor.otherΚουτσουπάκης, Κωνσταντίνος-
dc.date.accessioned2013-01-21T13:34:18Zen
dc.date.accessioned2013-05-16T06:25:23Z-
dc.date.accessioned2015-12-02T08:50:27Z-
dc.date.available2013-01-21T13:34:18Zen
dc.date.available2013-05-16T06:25:23Z-
dc.date.available2015-12-02T08:50:27Z-
dc.date.issued2002-04-17-
dc.identifier.citationJournal of the american chemical society, 2002, vol. 124, no.15, pp. 3814-3815en_US
dc.identifier.issn27863-
dc.identifier.urihttps://hdl.handle.net/20.500.14279/1127-
dc.description.abstractTime-resolved step-scan Fourier infrared spectroscopy has been used to study the CO-bound cbb 3-type cytochrome c oxidase from Pseudomonas stutzeri at room temperature. We observe a single band in the FTIR spectrum at 1956 cm -1 (β-form). The time-resolved data indicate that upon photolysis, CO is transferred from heme b 3 (v CO = 1956 cm -1) to CuB (v CO = 2064 cm -1). The decay of the 2065 cm -1 peak (t 1/2 = 120 ± 16 ms) and the development of the 1956 cm -1 peak (t 1/2 = 144 ± 8 ms ) suggest that formation of the Fe-CO complex is concurrent with the decay of the CuB-CO complex. The intensity ratio of the Fe-CO/CuB-CO (2.15) remains constant for all data points, and thus we conclude that no fraction of CO escapes the binuclear center at 293 Ken_US
dc.formatpdfen_US
dc.language.isoenen_US
dc.relation.ispartofJournal of the American Chemical Societyen_US
dc.rights© American Chemical Societyen_US
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/us/*
dc.subjectCarbon monoxideen_US
dc.subjectCopper compoundsen_US
dc.subjectFourier transform infrared spectroscopyen_US
dc.subjectCytochromeen_US
dc.subjectHemeen_US
dc.subjectIronen_US
dc.titleDecay of the transient Cu B-CO complex is accompanied by formation of the heme Fe-CO complex of cytochrome cbb 3-CO at ambient temperature: evidence from time-resolved fourier transform infrared spectroscopyen_US
dc.typeArticleen_US
dc.affiliationUniversity of Creteen
dc.collaborationUniversity of Creteen_US
dc.subject.categoryChemical Sciencesen_US
dc.journalsHybrid Open Accessen_US
dc.countryCyprusen_US
dc.subject.fieldNatural Sciencesen_US
dc.publicationPeer Revieweden_US
dc.identifier.doi10.1021/ja0169825en_US
dc.dept.handle123456789/54en
dc.relation.issue15en_US
dc.relation.volume124en_US
cut.common.academicyear2002-2003en_US
dc.identifier.spage3814en_US
dc.identifier.epage3815en_US
item.fulltextNo Fulltext-
item.cerifentitytypePublications-
item.grantfulltextnone-
item.openairecristypehttp://purl.org/coar/resource_type/c_6501-
item.openairetypearticle-
item.languageiso639-1en-
crisitem.journal.journalissn1520-5126-
crisitem.journal.publisherAmerican Chemical Society-
crisitem.author.deptDepartment of Chemical Engineering-
crisitem.author.deptDepartment of Chemical Engineering-
crisitem.author.facultyFaculty of Geotechnical Sciences and Environmental Management-
crisitem.author.facultyFaculty of Geotechnical Sciences and Environmental Management-
crisitem.author.orcid0000-0003-2771-8891-
crisitem.author.orcid0000-0001-9301-1021-
crisitem.author.parentorgFaculty of Geotechnical Sciences and Environmental Management-
crisitem.author.parentorgFaculty of Geotechnical Sciences and Environmental Management-
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