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https://hdl.handle.net/20.500.14279/9379| Title: | Photobiochemical Production of Carbon Monoxide by Thermus thermophilus ba3-Cytochrome c Oxidase | Authors: | Koutsoupakis, Constantinos Soulimane, Tewfik Varotsis, Constantinos |
Major Field of Science: | Natural Sciences | Field Category: | Earth and Related Environmental Sciences | Keywords: | FTIR spectroscopy;Biochemistry;Carbon monoxide;Heme proteins;Oxidoreductases | Issue Date: | 16-Feb-2015 | Source: | Chemistry a european journal, 2015, vol. 21, no. 13, pp. 4958-4961. | Volume: | 21 | Issue: | 13 | Start page: | 4958 | End page: | 4961 | Journal: | Chemistry a european journal | Abstract: | We report the photobiochemical production of carbon monoxide by a terminal ba3-cytochrome c oxidase from T. thermophilus HB8. FTIR and time-resolved step-scan FTIR spectroscopies were combined to probe this process and also monitor the concomitant binding of the produced gas to other intact ba3 molecules forming the ba3-CO complex. The activation of this mechanism by ba3-oxidase under visible excitation raises the question as to whether such a mechanism is physiologically relevant to the extreme environment in which it operates. | URI: | https://hdl.handle.net/20.500.14279/9379 | ISSN: | 15213765 | DOI: | 10.1002/chem.201406239 | Rights: | © Wiley-VCH Verlag GmbH & Co. KGaA Attribution-NonCommercial-NoDerivs 3.0 United States |
Type: | Article | Affiliation : | Cyprus University of Technology |
| Appears in Collections: | Άρθρα/Articles |
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