Please use this identifier to cite or link to this item:
https://hdl.handle.net/20.500.14279/23795
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Roydhouse, Mark D. | - |
dc.contributor.author | Motherwell, William B. | - |
dc.contributor.author | Constantinou, Achilleas | - |
dc.contributor.author | Gavriilidis, Asterios | - |
dc.contributor.author | Wheeler, Rob C. | - |
dc.contributor.author | Down, Kenneth D. | - |
dc.contributor.author | Campbell, Ian B. | - |
dc.date.accessioned | 2022-01-25T10:03:19Z | - |
dc.date.available | 2022-01-25T10:03:19Z | - |
dc.date.issued | 2013-04-21 | - |
dc.identifier.citation | RSC Advances, 2013, vol. 3, no. 15, pp. 5076 - 5082 | en_US |
dc.identifier.issn | 20462069 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.14279/23795 | - |
dc.description.abstract | The ozonolysis of several organic substrates to give carbonyl compounds, carboxylic acids and nicotinic acids in flow using a standard lab-scale flow system equipped with a cooled flow cell was examined. Alkyl and aryl alkenes showed good conversion (49-99%) to the corresponding aldehydes and ketones utilising an "in flow" quench of triphenylphosphine. The ozonolysis of either 2 or 3-substituted furans obtained furnished a variety of carboxylic acids including the pharmaceutically important oxetane-3-carboxylic acids in two steps from furan and oxetan-3-one. Substituted benzoic acids were generated with high yields in two steps from aryl iodides. The non-selective ozonolysis of quinolines is known to give 2,3-dicarbonyl substituted pyridines, herein we report the selective ozonolysis of 8-hydroquinoline to give 3-[(1E)-3-oxoprop-1- en-1-yl]pyridine-2-carboxylic acid using flow techniques. | en_US |
dc.format | en_US | |
dc.language.iso | en | en_US |
dc.relation.ispartof | RSC Advances | en_US |
dc.rights | © The Royal Society of Chemistry. | en_US |
dc.subject | Aromatic compounds | en_US |
dc.subject | Carboxylic acids | en_US |
dc.subject | Ketones | en_US |
dc.subject | Organic pollutants | en_US |
dc.subject | Pyridine | en_US |
dc.title | Ozonolysis of some complex organic substrates in flow | en_US |
dc.type | Article | en_US |
dc.collaboration | University College London | en_US |
dc.collaboration | GlaxoSmithKline | en_US |
dc.subject.category | Chemical Sciences | en_US |
dc.journals | Subscription | en_US |
dc.country | United Kingdom | en_US |
dc.subject.field | Natural Sciences | en_US |
dc.publication | Peer Reviewed | en_US |
dc.identifier.doi | 10.1039/c3ra00125c | en_US |
dc.identifier.scopus | 2-s2.0-84878038068 | en |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/84878038068 | en |
dc.contributor.orcid | #NODATA# | en |
dc.contributor.orcid | #NODATA# | en |
dc.contributor.orcid | #NODATA# | en |
dc.contributor.orcid | #NODATA# | en |
dc.contributor.orcid | #NODATA# | en |
dc.contributor.orcid | #NODATA# | en |
dc.contributor.orcid | #NODATA# | en |
dc.relation.issue | 15 | en_US |
dc.relation.volume | 3 | en_US |
cut.common.academicyear | 2012-2013 | en_US |
dc.identifier.spage | 5076 | en_US |
dc.identifier.epage | 5082 | en_US |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_6501 | - |
item.cerifentitytype | Publications | - |
item.openairetype | article | - |
crisitem.journal.journalissn | 2046-2069 | - |
crisitem.journal.publisher | Royal Society of Chemistry | - |
crisitem.author.dept | Department of Chemical Engineering | - |
crisitem.author.faculty | Faculty of Geotechnical Sciences and Environmental Management | - |
crisitem.author.orcid | 0000-0002-7763-9481 | - |
crisitem.author.parentorg | Faculty of Geotechnical Sciences and Environmental Management | - |
Appears in Collections: | Άρθρα/Articles |
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