Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.14279/23795
DC FieldValueLanguage
dc.contributor.authorRoydhouse, Mark D.-
dc.contributor.authorMotherwell, William B.-
dc.contributor.authorConstantinou, Achilleas-
dc.contributor.authorGavriilidis, Asterios-
dc.contributor.authorWheeler, Rob C.-
dc.contributor.authorDown, Kenneth D.-
dc.contributor.authorCampbell, Ian B.-
dc.date.accessioned2022-01-25T10:03:19Z-
dc.date.available2022-01-25T10:03:19Z-
dc.date.issued2013-04-21-
dc.identifier.citationRSC Advances, 2013, vol. 3, no. 15, pp. 5076 - 5082en_US
dc.identifier.issn20462069-
dc.identifier.urihttps://hdl.handle.net/20.500.14279/23795-
dc.description.abstractThe ozonolysis of several organic substrates to give carbonyl compounds, carboxylic acids and nicotinic acids in flow using a standard lab-scale flow system equipped with a cooled flow cell was examined. Alkyl and aryl alkenes showed good conversion (49-99%) to the corresponding aldehydes and ketones utilising an "in flow" quench of triphenylphosphine. The ozonolysis of either 2 or 3-substituted furans obtained furnished a variety of carboxylic acids including the pharmaceutically important oxetane-3-carboxylic acids in two steps from furan and oxetan-3-one. Substituted benzoic acids were generated with high yields in two steps from aryl iodides. The non-selective ozonolysis of quinolines is known to give 2,3-dicarbonyl substituted pyridines, herein we report the selective ozonolysis of 8-hydroquinoline to give 3-[(1E)-3-oxoprop-1- en-1-yl]pyridine-2-carboxylic acid using flow techniques.en_US
dc.formatpdfen_US
dc.language.isoenen_US
dc.relation.ispartofRSC Advancesen_US
dc.rights© The Royal Society of Chemistry.en_US
dc.subjectAromatic compoundsen_US
dc.subjectCarboxylic acidsen_US
dc.subjectKetonesen_US
dc.subjectOrganic pollutantsen_US
dc.subjectPyridineen_US
dc.titleOzonolysis of some complex organic substrates in flowen_US
dc.typeArticleen_US
dc.collaborationUniversity College Londonen_US
dc.collaborationGlaxoSmithKlineen_US
dc.subject.categoryChemical Sciencesen_US
dc.journalsSubscriptionen_US
dc.countryUnited Kingdomen_US
dc.subject.fieldNatural Sciencesen_US
dc.publicationPeer Revieweden_US
dc.identifier.doi10.1039/c3ra00125cen_US
dc.identifier.scopus2-s2.0-84878038068en
dc.identifier.urlhttps://api.elsevier.com/content/abstract/scopus_id/84878038068en
dc.contributor.orcid#NODATA#en
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dc.contributor.orcid#NODATA#en
dc.contributor.orcid#NODATA#en
dc.contributor.orcid#NODATA#en
dc.contributor.orcid#NODATA#en
dc.contributor.orcid#NODATA#en
dc.relation.issue15en_US
dc.relation.volume3en_US
cut.common.academicyear2012-2013en_US
dc.identifier.spage5076en_US
dc.identifier.epage5082en_US
item.fulltextNo Fulltext-
item.languageiso639-1en-
item.grantfulltextnone-
item.openairecristypehttp://purl.org/coar/resource_type/c_6501-
item.cerifentitytypePublications-
item.openairetypearticle-
crisitem.journal.journalissn2046-2069-
crisitem.journal.publisherRoyal Society of Chemistry-
crisitem.author.deptDepartment of Chemical Engineering-
crisitem.author.facultyFaculty of Geotechnical Sciences and Environmental Management-
crisitem.author.orcid0000-0002-7763-9481-
crisitem.author.parentorgFaculty of Geotechnical Sciences and Environmental Management-
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