Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.14279/20929
DC FieldValueLanguage
dc.contributor.authorMatsia, Sevasti-
dc.contributor.authorMenelaou, Melita-
dc.contributor.authorHatzidimitriou, Antonios-
dc.contributor.authorTangoulis, Vassilis-
dc.contributor.authorLalioti, Nikolia-
dc.contributor.authorIoannidis, Nikolaos E.-
dc.contributor.authorBlömer, Laura-
dc.contributor.authorKersting, Berthold-
dc.contributor.authorSalifoglou, Athanasios-
dc.date.accessioned2021-02-23T12:30:41Z-
dc.date.available2021-02-23T12:30:41Z-
dc.date.issued2020-08-16-
dc.identifier.citationEuropean Journal of Inorganic Chemistry, no.30, pp. 2919-2940en_US
dc.identifier.issn14341948-
dc.identifier.urihttps://hdl.handle.net/20.500.14279/20929-
dc.description.abstractemperature-sensitive crystalline phases, pertaining to discrete clusters of binary and ternary Co(II,III):iminodipropanol:(N,N'-aromatic binder) systems, were prepared. The rich structural speciation of such systems in alcoholic media and their unique structural, magnetic, and spectroscopic profiles have been demonstrated. The need to understand the chemical reactivity of such complex ternary Co(II)-(1,1'-iminodi-2-propanol) systems, in the presence of N,N'-aromatic chelators 2,2'-bipyridine and 1,10-phenanthroline and aromatic binder 4,4'-bipyridine in methanol, led to the synthetic development of well-defined hybrid metal-organic materials with discrete spectroscopic, structural, electrochemical, and magnetic properties. The surprisingly plethoric family of the prepared mononuclear-trinuclear-tetranuclear Co(II,III) clusters was characterized through elemental analysis, FT-IR, and X-ray crystallography. Enrichment of their physicochemical profile originated from electrochemical, optical (UV/Vis, luminescence), magnetic, and EPR studies, unequivocally supporting their structural formulation. Collectively, the experimentally and theoretically (Bond-Valence-Sum, Hirshfeld) perused structures project the influence of molecular stoichiometry and temperature on targeted synthetic efforts toward crystal engineering of discrete Co(II,III)-center assemblies, exemplifying structure-reactivity correlations and magneto-optical-structural attributes.en_US
dc.language.isoenen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.rights© 2020 WILEY-VCH Verlagen_US
dc.subjectCluster compoundsen_US
dc.subjectCobalten_US
dc.subjectMagnetic propertiesen_US
dc.subjectMetal-organic materialsen_US
dc.subjectStructure-activity relationshipsen_US
dc.subjectSynthesis designen_US
dc.titleTemperature-Sensitive Structural Speciation of Cobalt-Iminodialcohol-(N,N'-Aromatic Chelator) Systems: Lattice Architecture and Spectrochemical Propertiesen_US
dc.typeArticleen_US
dc.collaborationAristotle University of Thessalonikien_US
dc.collaborationUniversity of Patrasen_US
dc.collaborationInstitute of Nanoscience and Nanotechnologyen_US
dc.collaborationUniversität Leipzigen_US
dc.subject.categoryChemical Engineeringen_US
dc.journalsSubscriptionen_US
dc.countryGreeceen_US
dc.countryCyprusen_US
dc.countryGermanyen_US
dc.subject.fieldNatural Sciencesen_US
dc.publicationPeer Revieweden_US
dc.identifier.doi10.1002/ejic.202000435en_US
dc.relation.issue30en_US
cut.common.academicyear2020-2021en_US
dc.identifier.spage2919en_US
dc.identifier.epage2940en_US
item.grantfulltextnone-
item.openairecristypehttp://purl.org/coar/resource_type/c_6501-
item.fulltextNo Fulltext-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.openairetypearticle-
crisitem.author.deptDepartment of Mechanical Engineering and Materials Science and Engineering-
crisitem.author.deptDepartment of Mechanical Engineering and Materials Science and Engineering-
crisitem.author.facultyFaculty of Engineering and Technology-
crisitem.author.facultyFaculty of Engineering and Technology-
crisitem.author.orcid0000-0001-7845-8802-
crisitem.author.orcid0000-0001-7845-8802-
crisitem.author.parentorgFaculty of Engineering and Technology-
crisitem.author.parentorgFaculty of Engineering and Technology-
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