Please use this identifier to cite or link to this item:
https://hdl.handle.net/20.500.14279/19122
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Nicolaou, Maria | - |
dc.contributor.author | Drouza, Chryssoula | - |
dc.contributor.author | Keramidas, Anastasios D. | - |
dc.date.accessioned | 2020-10-09T11:54:42Z | - |
dc.date.available | 2020-10-09T11:54:42Z | - |
dc.date.issued | 2019 | - |
dc.identifier.citation | New Journal of Chemistry, 2019, vol. 43, no. 45, pp. 17595-17602 | en_US |
dc.identifier.issn | 13699261 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.14279/19122 | - |
dc.description.abstract | Three unique mixed-valence polyoxofluorovanadate clusters have been synthesized through a facile preparation process. The structure of these clusters is controlled by the addition of organic ligands. Single-crystal X-ray diffraction revealed that the clusters have the formula (XyH2)4[VV10VIV4O14(μ-O)10(μ3-O)10(μ3-F)2F4] (1), (Xy = m-xylylenediamine), (pyH)4(H)2[VV10VIV2O12(μ-O)8(μ3-O)10(μ3-F)2(pic)2] (2) and (pyH)4(H)3(Na+)[VV7VIV2O9(μ-O)8(μ3-O)4(μ5-F)(pic)4]2 (3), (py = pyridine, pic− = picolinate), with 2 and 3 representing the first examples of polyoxofluorovanadate clusters coordinated to a chelating ligand. The electron paramagnetic resonance (EPR) spectroscopy of 1 revealed that the spins of the VIV centers are coupled to each other, in contrast to the isolated spins of the isostructural [VV12VIV2O16(μ-O)10(μ3-O)10(μ3-F)2(L)2]6−, where L: im = imidazole (4); py (5). The trigonal bipyramidal coordinated VV atoms of 1, 4 and 5 mimic the structure of the active site of the vanadium dependent peroxidases and 4 and 5 exhibit peroxidase like activity. | en_US |
dc.format | en_US | |
dc.language.iso | en | en_US |
dc.relation.ispartof | New Journal of Chemistry | en_US |
dc.rights | © The Royal Society of Chemistry | en_US |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Bis(Acetylacetonato)Oxovanadium(IV) | en_US |
dc.subject | Vanadium Compounds | en_US |
dc.subject | Oxovanadium IV | en_US |
dc.title | Controlled one pot synthesis of polyoxofluorovanadate molecular hybrids exhibiting peroxidase like activity | en_US |
dc.type | Article | en_US |
dc.collaboration | University of Cyprus | en_US |
dc.collaboration | Cyprus University of Technology | en_US |
dc.subject.category | Chemical Sciences | en_US |
dc.journals | Subscription | en_US |
dc.country | Cyprus | en_US |
dc.subject.field | Natural Sciences | en_US |
dc.publication | Peer Reviewed | en_US |
dc.identifier.doi | 10.1039/C9NJ01999E | en_US |
dc.relation.issue | 45 | en_US |
dc.relation.volume | 43 | en_US |
cut.common.academicyear | 2019-2020 | en_US |
dc.identifier.spage | 17595 | en_US |
dc.identifier.epage | 17602 | en_US |
item.openairetype | article | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.fulltext | No Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_6501 | - |
item.grantfulltext | none | - |
crisitem.author.dept | Department of Agricultural Sciences, Biotechnology and Food Science | - |
crisitem.author.faculty | Faculty of Geotechnical Sciences and Environmental Management | - |
crisitem.author.orcid | 0000-0002-2630-4323 | - |
crisitem.author.parentorg | Faculty of Geotechnical Sciences and Environmental Management | - |
crisitem.journal.journalissn | 1369-9261 | - |
crisitem.journal.publisher | Royal Society of Chemistry | - |
Appears in Collections: | Άρθρα/Articles |
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