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dc.contributor.authorOhta, Takehiro-
dc.contributor.authorKitagawa, Teizo-
dc.contributor.authorVarotsis, Constantinos-
dc.contributor.otherΒαρώτσης, Κωνσταντίνος-
dc.date.accessioned2013-01-21T11:53:41Zen
dc.date.accessioned2013-05-16T06:25:19Z-
dc.date.accessioned2015-12-02T10:05:41Z-
dc.date.available2013-01-21T11:53:41Zen
dc.date.available2013-05-16T06:25:19Z-
dc.date.available2015-12-02T10:05:41Z-
dc.date.issued2007-03-09-
dc.identifier.citationAngewandte chemie - International edition, 2007, vol. 46, no. 13, pp. 2210-2214.en_US
dc.identifier.issn14337851-
dc.identifier.urihttps://hdl.handle.net/20.500.14279/1463-
dc.description.abstractNO laughing matter: The enzymatic production of laughing gas (N 2O) from two molecules of NO requires the formation of the N-N bond and the subsequent cleavage of the N-OH bond. Resonance Raman spectroscopic studies have now provided evidence for the formation of the key intermediate, the hyponitrite species (see the optimized molecular structure), in the heme a3 Fe-CuB binuclear center of ba3- oxidoreductase from Thermus thermophilus. (Figure Presented)en_US
dc.formatPdfen_US
dc.language.isoenen_US
dc.relation.ispartofAngewandte chemie - International editionen_US
dc.rights© Wiley-VCH Verlag GmbH & Co. KGaAen_US
dc.subjectEnzymesen_US
dc.subjectNitric oxideen_US
dc.subjectMetalloenzymesen_US
dc.subjectRaman spectroscopyen_US
dc.subjectChemical bondsen_US
dc.subjectOxidationen_US
dc.subjectCopperen_US
dc.subjectHemeen_US
dc.subjectChemistryen_US
dc.titleThe structure of the hyponitrite species in a heme Fe-Cu binuclear centeren_US
dc.typeArticleen_US
dc.affiliationUniversity of Creteen
dc.collaborationUniversity of Creteen_US
dc.journalsSubscriptionen_US
dc.countryGreeceen_US
dc.subject.fieldEngineering and Technologyen_US
dc.publicationPeer Revieweden_US
dc.identifier.doi10.1002/anie.200602963en_US
dc.dept.handle123456789/54en
dc.relation.issue13en_US
dc.relation.volume46en_US
cut.common.academicyear2007-2008en_US
dc.identifier.spage2210en_US
dc.identifier.epage2214en_US
item.grantfulltextnone-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.openairecristypehttp://purl.org/coar/resource_type/c_6501-
item.openairetypearticle-
item.fulltextNo Fulltext-
crisitem.journal.journalissn1521-3773-
crisitem.journal.publisherWiley-
crisitem.author.deptDepartment of Chemical Engineering-
crisitem.author.facultyFaculty of Geotechnical Sciences and Environmental Management-
crisitem.author.orcid0000-0003-2771-8891-
crisitem.author.parentorgFaculty of Geotechnical Sciences and Environmental Management-
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