Benzene hydrogenation over ni/ai2O3 catalysts prepared by conventional and sol-gel techniques

Abstract

Nickel supported on alumina catalysts have been prepared using various synthesis methods (dry impregnation, co-precipitation, sol-gel) and evaluated for the hydrogenation of benzene contained in gasoline. The evaluation was carried out in a laboratory scale high pressure fixed bed reactor fed with a stream of surrogated reformate gasoline consisted by a mixture of hexane, benzene and toluene. All catalysts have been characterized by the joint use of various physicochemical characterization methods (XRF, BET, TGA, SEM, XRD, UV-vis DRS and XPS) in order to correlate their catalytic performances to their physicochemical properties. The results obtained revealed that sol-gel procedure, especially when it is followed by supercritical drying (aerogel), produced the most promising catalysts for the aforementioned catalytic process. Sol-gel methodology ensured the best compromise between dispersion of the nickel phase and its interaction with the support surface. Co-precipitated catalysts exhibited important activities but lower than those of the sol-gel catalysts. The catalyst prepared by dry impregnation proved to be the less active. Calcination of the catalysts before their activation by reduction decreased their activities.