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Title: Synergistic effects of buffer layer processing additives for enhanced hole carrier selectivity in inverted Organic Photovoltaics
Authors: Savva, Achilleas 
Neophytou, Marios 
Koutsides, Charalambos 
Kalli, Kyriacos 
Choulis, Stelios A. 
Major Field of Science: Engineering and Technology
Field Category: Electrical Engineering - Electronic Engineering - Information Engineering
Keywords: Interfaces;Inverted organic solar cells;PEDOT:PSS buffer layers;Printed electronics;Processing additives;Solution based electronic materials
Issue Date: Nov-2013
Source: Organic Electronics, 2013, vol. 14, no. 11, pp. 3123-3130
Volume: 14
Issue: 11
Start page: 3123
End page: 3130
Journal: Organic Electronics 
Abstract: Solution based inverted Organic Photovoltaic (OPVs) usually use Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) derivatives combined with pristine processing additives as hole selective contact on top of the hydrophobic conjugated polymer:fullerene active layer. In this study, PEDOT:PSS based hole selective contact is treated with two different boiling point additives, 2,5,8,11-tetramethyl-6-dodecyn-5,8-diol ethoxylate (Dynol) and Zonyl FS-300 fluorosurfactant (Zonyl). Although corresponding inverted OPVs using the above PEDOT:PSS:Additives show similar power conversion efficiency (PCE) values, the mechanisms of their implementation on inverted OPV operation are not identical. By understanding the synergistic effects of PEDOT:PSS processing additives on the hole selectivity of inverted OPVs we demonstrate a novel combination of PEDOT:PSS additives mixture as an effective route to further increase the hole selectivity, reliability andpower conversion efficiency of inverted OPVs.
ISSN: 1566-1199
DOI: 10.1016/j.orgel.2013.07.024
Collaboration : Cyprus University of Technology
Rights: © Elsevier
Type: Article
Appears in Collections:Άρθρα/Articles

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