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Title: Structure, stability and bonding of ternary transition metal nitrides
Authors: Matenoglou, G. M.
Lekka, Christina E.
Koutsokeras, Loukas E. 
Keywords: Materials science;Titanium nitride;Diffraction;Hafnium;Niobium;Nitrides;Pulsed laser deposition
Issue Date: 2009
Publisher: Elsevier
Source: Surface and coatings technology, 2009, Volume 204, Issues 6–7, Pages 911–914
Abstract: Ternary transition metal nitrides have gained special attention in an effort to improve further the properties of the corresponding binary compounds. In this work, we present a comparative study of a very wide range of ternary transition metal nitrides of the form: TixMe1-xN and TaxMe1-xN (Me = Ti,Zr,Hf,Nb,Ta,Mo,W) over the whole x range (0 < x < 1) grown by Pulsed Laser Deposition (PLD) and by Dual Ion Beam Sputtering. We study the stability of the rocksalt structure in all these films experimentally and theoretically through ab-initio calculations. We investigate the validity of Vegard's rule and the effect of growth-dependent stresses to the lattice constant
ISSN: 02578972
Rights: © 2009 Elsevier B.V. All rights reserved
Type: Article
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