Please use this identifier to cite or link to this item: https://ktisis.cut.ac.cy/handle/10488/6584
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dc.contributor.authorPinakoulaki, Eftychiaen
dc.contributor.authorVarotsis, Constantinos-
dc.contributor.otherΠινακουλάκη, Ευτυχίαen
dc.contributor.otherΒαρώτσης, Κωνσταντίνος-
dc.date.accessioned2013-01-17T11:32:44Zen
dc.date.accessioned2013-05-16T06:25:22Z-
dc.date.accessioned2015-12-02T10:13:05Z-
dc.date.available2013-01-17T11:32:44Zen
dc.date.available2013-05-16T06:25:22Z-
dc.date.available2015-12-02T10:13:05Z-
dc.date.issued2008en
dc.identifier.citationJournal of inorganic biochemistry, 2008, Volume 102, Issue 5-6, Pages 1277-1287en
dc.identifier.issn01620134en
dc.identifier.urihttp://ktisis.cut.ac.cy/handle/10488/6584en
dc.description.abstractThe understanding of the dynamics and conformational control involved in the interplay between structure and function of nitric oxide reductase (Nor) and heme-copper oxidoreductases in their function to convert nitric oxide (NO) to nitrous oxide (N2O) is of fundamental importance in bioenergetics. We have applied resonance Raman spectroscopy to investigate the NO ligation/deligation reactions and the extent of communication between the metal centers at the heme a3-CuB site of heme-copper oxidases and of the heme Fe-non-heme Fe in Nor. The present study provides information of the electronic and vibrational structure of intermediates, and thus, it forms the basis for an atomic-level description of the key steps in the N-N bond formation and the N-O bond cleavage mechanism. The present experiments provide evidence as to the validity of the proposed hypothesis of the common evolutionary origin of aerobic respiration and bacterial denitrificationen
dc.language.isoenen
dc.publisherElsevieren
dc.rights© 2008 Elsevier Inc. All rights reserveden
dc.subjectNitric oxideen
dc.subjectBacteriaen
dc.subjectCopperen
dc.subjectCytochrome ben
dc.subjectIron ionsen
dc.subjectOxidoreductasesen
dc.subjectDenitrificationen
dc.titleNitric oxide activation and reduction by heme-copper oxidoreductases and nitric oxide reductaseen
dc.typeArticleen
dc.affiliationCyprus University of Technologyen
dc.identifier.doi10.1016/j.jinorgbio.2008.01.014-
dc.dept.handle123456789/54en
item.grantfulltextnone-
item.fulltextNo Fulltext-
item.languageiso639-1other-
crisitem.author.deptDepartment of Environmental Science and Technology-
crisitem.author.facultyFaculty of Geotechnical Sciences and Environmental Management-
crisitem.author.orcid0000-0003-2771-8891-
crisitem.author.parentorgFaculty of Geotechnical Sciences and Environmental Management-
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