Please use this identifier to cite or link to this item: https://ktisis.cut.ac.cy/handle/10488/10930
Title: Novel combustion synthesis of carbon foam‑aluminum fluoride nanocomposite materials
Authors: Kostoglou, Nikolaos 
Emre Gunduz, I. 
Isik, Tugba 
Ortalan, Volkan 
Constantinides, Georgios 
Kontos, Athanassios G. 
Steriotis, Theodore 
Ryzhkov, Vladislav 
Bousser, Etienne 
Matthews, Etienne 
Doumanidis, Etienne 
Mitterer, Christian 
Rebholz, Christian 
Major Field of Science: Natural Sciences
Field Category: Chemical Sciences
Keywords: Aluminum fluoride;Carbon foam;Combustion synthesis;Nanocomposite;Porous material
Issue Date: 15-Apr-2018
Source: Materials and Design, 2018, vol. 144, pp. 222-228
Volume: 144
Start page: 222
End page: 228
Journal: Materials & Design 
Abstract: The facile, rapid and bulk production of composite materials consisting of carbon nanostructures doped with metal-based compounds has been a significant challenge for various research areas where such types of materials can be applied, including catalysis, energy storage and water purification. In this work, a carbon foam‑aluminum fluoride composite (C-AlF3) was developed by adopting a combustion synthesis approach, which is an attractive alternative to wet chemical methods usually employed for such purposes. The flame ignition and combustion of a solid-state mixture comprising a fluoropolymer and nano-sized Al powder leads to the formation of a porous carbon foam network doped with dispersed cubic-like AlF3 nanoparticles (100 to 500 nm in size), as observed by high-resolution microscopy methods. Selective area electron diffraction and X-ray diffraction studies revealed a rhombohedral α-AlF3 crystal structure for these embedded particles, while micro-Raman spectroscopy indicated typical carbonaceous features for the foamy matrix. The C-AlF3 composite also showed a combination of micro-, meso- and macro-porous characteristics (i.e. pore sizes in the nanometer scale) based on the analysis of N2 sorption data collected at 77 K. The findings of this study provide useful insights for further research on carbon-based nanocomposite materials prepared via direct combustion synthesis routes.
ISSN: 0264-1275
DOI: 10.1016/j.matdes.2018.02.021
Rights: © Elsevier
Type: Article
Affiliation : Montanuniversitӓt Leoben 
University of Cyprus 
Purdue University 
Cyprus University of Technology 
National Center for Scientific Research Demokritos 
Fibrtec Incorporation 
University of Manchester 
Nazarbayev University 
Khalifa University of Science and Technology 
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