Non-Embedded Silver Nanowires/Antimony-Doped Tin Oxide/Polyethylenimine Transparent Electrode for Non-Fullerene Acceptor ITO-Free Inverted Organic Photovoltaics

Abstract

Indium tin oxide (ITO)-free solution-processed transparent electrodes are an essential component for the low-cost fabrication of organic optoelectronic devices. High-performance silver nanowires (AgNWs) ITO-free inverted organic photovoltaics (OPVs) usually require a AgNWs-embedded process. A simple cost-effective roll-to-roll production process of inverted ITO-free OPVs with AgNWs as a bottom transparent electrode requires solution-based thick metal oxides as carrier-selective contacts. In this reported study, we show that a solution-processed antimony-doped tin oxide (ATO)/polyethylenimine (PEI) electron-selective contact incorporated on the top of non-embedded AgNWs provides a high-performance ITO-free bottom electrode for non-fullerene acceptor (NFA) inverted OPVs.