Please use this identifier to cite or link to this item:
https://hdl.handle.net/20.500.14279/24378
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Loizou, Maria | - |
dc.contributor.author | Hadjiadamou, Ioanna | - |
dc.contributor.author | Drouza, Chryssoula | - |
dc.contributor.author | Keramidas, Anastasios D. | - |
dc.contributor.author | Simos, Yannis V. | - |
dc.contributor.author | Peschos, Dimitrios | - |
dc.date.accessioned | 2022-02-18T12:04:25Z | - |
dc.date.available | 2022-02-18T12:04:25Z | - |
dc.date.issued | 2021-10-01 | - |
dc.identifier.citation | Inorganics, 2021, vol. 9, no. 10, articl. no. 73 | en_US |
dc.identifier.issn | 23046740 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.14279/24378 | - |
dc.description.abstract | Novel vitamin E chelate siderophore derivatives and their VV and FeIII complexes have been synthesised and the chemical and biological properties have been evaluated. In particular, the α-and δ-tocopherol derivatives with bis-methyldroxylamino triazine (α-tocTHMA) and (δ-tocDPA) as well their VV complexes, [V2VO3(α-tocTHMA)2] and [V2IVO3(δ-tocTHMA)2], have been synthesised and characterised by infrared (IR), nuclear magnetic resonance (NMR), electron paramagnetic resonance (EPR) and ultra violet-visible (UV-Vis) spectroscopies. The dimeric vanadium complexes in solution are in equilibrium with their respefrctive monomers, H2O + [V2VO2(μ-O)]4+ = 2 [VVO(OH)]2+. The two amphiphilic vanadium complexes exhibit enhanced hydrolytic stability. EPR shows that the complexes in lipophilic matrix are mild radical initiators. Evaluation of their biological activity shows that the compounds do not exhibit any significant cytotoxicity to cells. | en_US |
dc.format | en_US | |
dc.language.iso | en | en_US |
dc.relation.ispartof | Inorganics | en_US |
dc.rights | © The Author(s) | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Vanadium | en_US |
dc.subject | Vitamin E | en_US |
dc.subject | EPR | en_US |
dc.subject | Tocopherol | en_US |
dc.subject | 51V NMR | en_US |
dc.title | Vanadium(V) complexes with siderophore vitamin e-hydroxylamino-triazine ligands | en_US |
dc.type | Article | en_US |
dc.collaboration | University of Cyprus | en_US |
dc.collaboration | Cyprus University of Technology | en_US |
dc.collaboration | University of Ioannina | en_US |
dc.subject.category | Agriculture Forestry and Fisheries | en_US |
dc.journals | Open Access | en_US |
dc.country | Cyprus | en_US |
dc.country | Greece | en_US |
dc.subject.field | Agricultural Sciences | en_US |
dc.publication | Peer Reviewed | en_US |
dc.identifier.doi | 10.3390/inorganics9100073 | en_US |
dc.identifier.scopus | 2-s2.0-85116487277 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/85116487277 | - |
dc.relation.issue | 10 | en_US |
dc.relation.volume | 9 | en_US |
cut.common.academicyear | 2020-2021 | en_US |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.openairecristype | http://purl.org/coar/resource_type/c_6501 | - |
item.openairetype | article | - |
item.languageiso639-1 | en | - |
crisitem.author.dept | Department of Agricultural Sciences, Biotechnology and Food Science | - |
crisitem.author.faculty | Faculty of Geotechnical Sciences and Environmental Management | - |
crisitem.author.orcid | 0000-0002-2630-4323 | - |
crisitem.author.parentorg | Faculty of Geotechnical Sciences and Environmental Management | - |
Appears in Collections: | Άρθρα/Articles |
Files in This Item:
File | Description | Size | Format | |
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inorganics-09-00073-v2.pdf | 6.75 MB | Adobe PDF | View/Open |
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